Archive for the ‘Materials’ category

Concrete Nanotubes and Long Lasting Concrete

February 1st, 2010

The manufacturing of cement produces about 5% of the world’s CO2 output.   Analysis has concluded that producing a single pound of cement generates .73 – .99 pounds of CO2.[i] 

The concrete that is so ubiquitous in our highways is 7% to 15% cement by total weight.  All of this concrete is susceptible to the freeze and thaw cycle as well as general wear and tear.  Anything that can be done to reduce the carbon footprint of concrete by increasing the times between repairs and replacement would be a major win for both the concrete industry and sustainability movement.

This is great news:

Northwestern [University] engineer Surendra Shahand and his team are adapting cutting-edge technology to improve a decidedly low-tech substance by infusing concrete with carbon nanotubes. Carbon nanotubes are strong, flexible pipe-like arrangements of carbon atoms too small to be seen by most microscopes.

“We use 2 tons per capita per year of concrete, can you imagine that?” Shah said. Worldwide, that translates into nearly 12 billion tons of concrete per year. And, as countries such as China and India continue to develop, that amount will almost certainly go up.

That’s where Shah’s work comes in. At the atomic scale, concrete looks like a bunch of tennis balls packed together. The chemical reactions that take place between cement and water create nanovoids, or spaces, between the balls. This means that chips, cracks and potholes actually start at the nanoscale.

Using carbon nanotubes would make the concrete nearly impenetrable, greatly extending the lifespan of roads, bridges and buildings.

“If you can make concrete very impermeable, so that salt doesn’t go through, then you can extend the life to a hundred years rather than 20,” Shah said.

Not surprisingly, this new technology isn’t cheap. But when that higher price tag is spread out over a much longer lifespan, it could become cost-effective. And this doesn’t factor in the reduced cost to the environment.

“We have to include all of this, not only the material cost,” Shah said.

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As stated, the technology is expensive, but sounds very promising.  And frankly, we have grown accustomed to cheap materials only because they do not include the true, long term negative externalities, so some sort of Pigovian tax to cover these negative consequences doesn’t strike me as particularly bad. From this point of view, the extra cost of the nanotube concrete might be worth it but everyone knows that only the truly committed would be willing to pay the extra upfront costs. Luckily, prices should be expected to come down as the industry accepts the product, production figures rise, and marginal costs fall.


[i] http://www.concretethinker.com/Papers.aspx?DocId=312

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Building a sustainable urban environment on a dirty foundation

January 19th, 2010

While the intentions of refashioning urban areas into complete streets are noble, the immediate effect is an increase in pollution stemming from the new construction. While one could reasonably argue that the long term gains from the reconstruction outweigh the pollution, a) it is still important to recognize the damage and b) becoming cognizant of the negative effects lets you plan ahead and build a complete street upon a greener foundation.

A complete street might require: new sidewalks, repaved lanes, and special lanes for busses. All of which requires aggregate rock, cement or asphalt.

For something like a major road, the carbon footprint adds up very quickly. In total, a single 1 lane-mile of freeway pavement can consume up to 12,000 tons of raw materials and emit enough pollution in terms of Global Warming Potential to equal 1200 tons of CO2.[i]

Starting from the bottom, beneath of all of the pavement, there typically lays a layer of aggregate rock – the most mined material on earth. Though recycled aggregates are available, most aggregates are fresh. Each ton of that rock must be hauled in diesel truck and then spread over the sight using special equipment, burning hundreds of gallons of diesel fuel, releasing tons of emissions and putting excess strain on construction budgets. Per cubic meter (which weighs about 2.2 tons), this is will be the most environmentally friendly layer but will still contain 15.8kg of CO2.[ii] That doesn’t sound like a lot until you realize that given a subbase 8 meters wide (2 lanes), and .2 meters deep, per mile this adds up to 89,695 pounds of CO2. That’s 20 metric tons of global warming causing pollution per lane per mile just from the road’s foundational layer.

Next, there’s the paving, the really dirt part.

Paving with either asphalt concrete or cement concrete requires a number of diesel-burning construction machinery such as concrete mixer trucks, asphalt pavers, and vibrating rollers. Per ton of material, concrete requires .5 gallons of diesel, hot mix asphalt requires 2.9. [iii]

According to the Athena study, at installation asphalt containing 20% reclaimed asphalt pavement (RAP) will posses about 118 pounds of CO2 per ton (1 cubic meter weighs 2420 kg and posses 129.74 kg of embodied CO2).

The other option, concrete paving, is much more energy-intensive during the construction process. The industry as a whole employs .1% of the US labor force but generates 1.5% – 2.0% of all US CO2 emissions.[iv],[v] One report found that that to produce and lay down enough cement for a 1km (.62 miles), 4 lane highway required the equivalent energy of 1049 tons of oil.[vi] And emissions, when measured in CO2 equivalence (Different green house gasses have different strengths i.e. one kilogram of nitrous oxide, N2O, has as much global warming power as 310kg of CO2) range from 308lbs per ton of cement concrete to 440kg per ton of continues reinforced concrete.[vii]

You can see how this very quickly can add up, especially considering at the US alone builds at least 15,000 lane miles per year.[viii] Finding alternative methodologies is critical if we are to build new roads or to rebuild improperly utilized urban areas in a manner that is congruent with sustainable living.


[i] http://pavementinteractive.org/images/6/6c/Greenroads_summary.pdf

[ii] http://www.mrmca.com/paving/athena.pdf

[iii] http://www.acpa.org/Downloads/QDs/QD023P%20-%20Conserving%20Fuel%20in%20the%20Road.pdf

[iv] http://www.cement.org/econ/industry.asp

[v] http://www.concretethinker.com/technicalbrief/Concrete-Cement-CO2.aspx

[vi] http://www.lcarc.re.kr/Korean/staff%20list/papers/ASCE_2003.pdf

[vii] http://www.pavementpreservation.org/publications/getfile.php?journal_id=1283

[viii] http://www.bts.gov/publications/national_transportation_statistics/html/table_01_01.html

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